Offensive/Defensive: Difference
I think the difference is in the stats of the infusion. There is Vital infusion and it goes into defensive slots. While there is Precise infusion and it goes in offensive infusion slots.
As I understand it, Philosophers stones make offensive, Crystals make defensive.
The stat combinations on the back piece you’re talking about, with magic find, were crafted with vicious claws, which make exotic explorers (magic find) gear.
I thing the t6 material you use, will vary the stat combinations, powerful blood for instance, I’m guessing will make pow/pre/crit back pieces, like the beserkers exotic gear it makes.