Q:
Is it possible to unbind LG/AS gear?
A:
For Ascended gear: upgrading a piece of Ascended gear via the MF (backpieces, rings) will make it account bound. This applies ONLY to upgrades made via the MF- infusing an item by putting an infusion into an infusion slot will not unbind it.
For legendaries: they can be moved from character through a roundabout way that requires gems.
1.) Transmute legendary onto a white item, keeping the stats of the white item and the skin of the legendary. Do NOT buy a white item from an NPC weaponsmith, as those whites are soulbound. Buy one from the TP.
2.) The transmuted legendary should now be account bound. Move it to the character you want to transfer it to through the bank.
3.) Use a transmutation splitter (300 gems per) on the transmuted item. It will give you back your legendary (now soulbound to the character you used the splitter with), the white item, and the sigil.
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Nice, thanks for the info