Missing skill in Mists
The new skills need to be purchased, no matter what mode. Maybe the skill point scrolls drop in PvP, or you can purchase them with glory, I’m not sure as I don’t PvP.
Edit: From December 10th Game Update Notes
Profession Skills
We are introducing a new healing skill for each profession. These skills are locked in both PvE and PvP. They can be unlocked by purchasing them with 25 skill points. When a skill is unlocked on a character, it becomes unlocked in both PvE and PvP.
(edited by Inculpatus cedo.9234)
Also you can buy Tome of Knowledge for glory, that gives you one level. If you have already lvl 80, you will still get one level and additional skillpoint. It means, that you can unlock this skill (and many more that will come in the future) playing only in PVP mode.